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This is the same principle behind why recombinant protein biologics (monoclonal antibodies, insulin analogues) are never shaken: air-water interfacial agitation unfolds polypeptide chains that then reassemble into non-native oligomers or fibrils

Bierman JC, Laughlin T, Tamura M, et al

I wish you well I respect your judgement over mine, but I haven't found any deterioration in ampoules that have been stored in the dark but are a year beyond their date